ACCESSORIES

Ruby Balls

Corundum, chromium-doped alumina — Al₂O₃:Cr³⁺. In situ pressure calibration for diamond anvil cells.

The BETSA® ruby balls

BETSA ruby balls sample — BETSA® ruby balls, showing their perfect spherical shape and their wide size distribution from 3 to 50 μm.

BETSA® has supplied the high-pressure community with ruby balls for in situ pressure measurement for over 35 years.

The chromium doping of 3300 ppm is constant and optimal for obtaining the highest R1 line intensity, so as to measure the highest possible pressures for a given laser wavelength.

Typically, BETSA® ruby balls allow you to measure pressures as high as 90 GPa using a 532 nm laser at 10 mW, and up to 120 GPa using a 405 nm laser at 50 mW.

Ruby fluorescence line intensities versus Cr3+ doping — Ruby R1 (694 nm) and R2 (774 nm) fluorescence line intensities as a function of Cr³⁺ doping (NNT: 1990INPG4204). The best yield is obtained for a 3300 ppm doping — the doping of the BETSA® ruby balls.

BETSA® delivers its ruby balls on a holder that makes them safe and easy to carry, to observe under a microscope and to pick up individually so as to place them inside a DAC. The 10 mg quantity we propose is ideal for not saturating the holder while keeping it convenient. This 10 mg corresponds to several thousand balls, so a single holder provides a high-pressure laboratory with the ruby balls it needs for many years.

How they are made

Their sphericity arises from their preparation method: molten doped alumina is pushed through a jet so that small droplets form and solidify while “in flight”. Unlike crushing large pieces of ruby, this method provides single-crystalline spheres with little internal stress, free of dislocations and featuring a smooth, non-scattering surface. To remove any remaining internal stress, we heat-treat our ruby balls several times. This way, our ruby balls provide clear and narrow R1 and R2 fluorescence lines.